摘要
A new metal-organic coordination polymer [Zn(ipt)(im)2]2n·3nH2O 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group P2(1/n) with a = 10.653(3), b = 17.891(6), c = 10.743(4)A^°,β= 117.093(5)°, V= 1822.9(10) A^°3, Mr= 413.65, Dc = 1.507 g/cm^3,/t(MoKa) = 1.390 mm^-1, F(000) = 840, Z = 4, the final R = 0.0444 and wR = 0.1066 for 2434 observed reflections (I〉 2σ(I)). Furthermore, compound 1 shows blue photoluminescent property at room temperature.
A new metal-organic coordination polymer [Zn(ipt)(im)2]2n·3nH2O 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group P2(1/n) with a = 10.653(3), b = 17.891(6), c = 10.743(4)A^°,β= 117.093(5)°, V= 1822.9(10) A^°3, Mr= 413.65, Dc = 1.507 g/cm^3,/t(MoKa) = 1.390 mm^-1, F(000) = 840, Z = 4, the final R = 0.0444 and wR = 0.1066 for 2434 observed reflections (I〉 2σ(I)). Furthermore, compound 1 shows blue photoluminescent property at room temperature.
基金
The project was supported by the Education Office of Jilin Province (No. 0047)