取代1,1'-联-2-萘酚在铜胺络合物催化作用下的氧化反应

Catalytic Oxidation Reaction of Substituted 1,1′-Bi-2-naphthols with Copper-Amine Complex

用CuCl2?2H2O与小分子的有机胺形成络合物,模拟氧化还原酶对多米诺式反应(Dominoreaction)进行催化反应,在氧气存在条件下,取代1,1'-联-2-萘酚化合物被氧化为二苯并呫吨类化合物,产物的结构经核磁共振、红外光谱及质谱进行确证.

The complex of CuCl2·2H2O with small molecular amine as a catalyst for Domino reaction, which was a mimic to oxidoreductase, was reported. Substituted 1,1＇-bi-2-naphthols were oxidized into dibenzoxanthenoids in the presence of O2. The structures of these compounds were characterized with ^1H NMR, IR and FAB-MS spectra.