CF_2自由基电子激发态解离通道的静力学分析

An Investigation on the Dissociation Statics of the Excitated Electronic States of CF_2 Radical

本文根据原子分子反应静力学的基本原理,利用对称性关联的方向性原则,研究了三原子CF2体系的可能解离通道.在轨道和自旋规则限制下,得到了母体自由基特定电子态与解离碎片电子态之间的对应关系,并具体给出了CF2自由基在不同电子态下可能的解离通道.

In this paper the possible dissociation channels of the excited electronic sate of CF2 radical were discussed based on the basic correlation rule. Considering principl he limit e of atomic and molecular reaction statics in terms of the symmetry of the orbital and spin correlation rule, the correspondence between the specific electronic state of the parent radical and the fragment were presented. The possible dissociation channels of different electron states of CF2 radical were obtained.