二乙基二硫代氨基甲酸钴[(C_5H_(10)NS_2)_3Co(Ⅲ)]的溶剂热合成、晶体结构及电化学性质

Solventthermal Synthesis,Crystal Structure and Electrochemical Property of Diethyldithiocarbamate Cobalt(Ⅲ) Complex

溶剂热法合成了二乙基二硫代氨基甲酸钴配合物[(C5H10NS2)3Co(Ⅲ)],并制备了其单晶。用X射线衍射法测定了晶体结构并结合晶体结构对配合物做了电化学研究。该化合物属于单斜晶系,C2/c空间群,晶胞参数a=1.417 1(3)nm,b=1.033 3(4)nm,c=1.711 4(5)nm,z=4,Dc=1.423 g.cm-3,μ=1.268 mm-1,F(000)=1 056,最终结构偏离因子R=0.032 1,ωR=0.086 4,S=1.070。

The title compound[ （C5 H10 NS2 ） 3 Co （ Ⅲ） 3 was synthesized by solventthermal method and was determined by single crystal X-ray diffraction. The electrochemical property of the complex was also investigated. The compound crystallizes in monoclinic crystal system,space group C2/c with a=1. 4171（3）nm,b=1. 033 3（4）nm,c=1. 711 4（5） nm, z=4, Dc=1. 423 g · cm^-3 , p=1. 268 mm^-1 , F（000）=1056. The final reflection factors were R=0. 0321, ωR=0. 086 4 and S=1. 070.