超临界技术在化学工业中的应用

Application of Supercritical Fluids Technology In Chemical Industry

介绍了超临界状态下物质体系的基本特性,对采用超临界CO2等流体技术在绿色有机合成方面进行的一些反应如:催化氢化反应、氧化反应、羧基化反应、酶催化反应等作了简单介绍。另外,对超临界水的特性及其在有机化学反应的应用,特别在废塑料油化等方面的应用作了较详细介绍。超临界流体技术在化学工业上一些领域的产业化业已实现,从现代化学工业的发展前景看,它在绿色化学反应方面具有很大的潜在优势和诱人的应用前景。

The new achievements and recent progress of supercritical carbon dioxide and supercritical water in chemical industry and organic chemical reaction, especially in catalytic hydrogenation, hydroformylation, free radical reaction, oxidation and enzymatic catalytic reaction and so on, were introduction. The technical characteristics of supercritical water and waste polyethylene degradation to oil in supercritical water , were also described in detail.