过氧化氢为氧源催化烯烃环氧化研究

Progress in Catalytic Epoxidation of Olefins with Hydrogen Peroxide

环境友好催化烯烃环氧化是催化氧化领域中的一大热点,过氧化氢作为一种理想的清洁氧源日益受到人们的重视。本文从匀相和多相催化两方面综述了近年来以过氧化氢为氧源催化烯烃环氧化研究的主要进展,对一些有很好工业化应用前景的反应体系作了详细介绍。

Environmentally benign catalytic epoxidation of olefins is one of the important aspects in catalytic oxidation field. Hydrogen peroxide as one of the ideal oxidant is used in many catalytic systems. In this paper, the recent progress in catalytic epoxidation of olefins with hydrogen peroxide, from the aspects of homogeneous and heterogeneous catalytic systems, is summarized, and some systems with prospect in industrial application are described in detail.