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纳米颗粒在火焰中聚结过程湍流稀释的数值模拟 被引量:1

Simulation of Dilution Effect Caused by Radial Eddy Dispersion in Process of Nanoparticle Coagulation in Flame
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摘要 针对TiO2纳米颗粒合成过程,利用CFD商业软件FLUENT及其自定义函数功能,模拟了燃烧室中湍流扩散火焰的温度场和组分场;把二氧化钛作为一种准气体,在颗粒动力学模型中考虑了火焰中径向湍流引起的稀释作用对颗粒聚结的影响,对产物颗粒直径、聚集块中颗粒的数目等进行了预测,并对结果进行了分析;同时与未加径向湍流稀释项的模拟进行了比较,得出湍流的稀释作用对颗粒的生长过程有一定的影响,并分析了火焰温度、先驱物载体气体、燃料、氧化剂流量等对生成颗粒或者颗粒聚集块的尺寸的影响。 By the commercial CFD-code FLUENT's functions, the temperature freld and the component field of the turbulent diffusion flame in combustor were simulated in view of the composition process of TiO2 nanoparticles. The effect of dilution caused by radial eddy dispersion in the flame, the growth process of titania nanoparticle synthesized in a diffusion flame of propane and oxygen were investigated, The particle size and the particle number in the outcome were calculated, analysed and compared, The results showed that the dilution caused by radial eddy dispersion in the flame increased the size of primary particles slightly, but still much smaller than experimental results,and the influence which the flame structure have on the character of particle is analyzed. Some probable reasons were given.
出处 《中国粉体技术》 CAS 2006年第2期29-33,共5页 China Powder Science and Technology
基金 大连理工大学材料学科基金资助
关键词 纳米颗粒 湍流扩散火焰 颗粒动力学 湍流稀释 nanoparticles turbulent diffusion flame fluid-particle dynamics dilution effects
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参考文献8

  • 1Zhu W,Pratsinis S E.Flame synthesis of nanosized powders[M].Chow G M,Gonsalves K E.Nanotechnology,ACS Symp.Ser,1996:622.
  • 2Kruis F E,Kusters KA,Pratsinis S E.A simple model for the evolution of the characteristics of aggregate particles undergoing coagulation and sintering[J].Aerosol Science and Technology,1993,19:514-526.
  • 3Johannessen.Implementing User-defined Scalars/Functions in Fluent-A practical example[R].Department of Chemical Engineering,Technical University of Denmark (1999).
  • 4Schild A,Gutsch A,MuhlenwegH.et al Simulation of nanoparticle production in premixed aerosol flow reactors by interfacing fluid mechanics and particle dynamics[J].Journal of Nanoparticle Research,1999,1:305-315.
  • 5Tue Johannessen,Sotiris E Prasinis,Hans Livbjerg.Computational fluid-particle dynamics for the flame synthesis of alumina particles[J].Chemical Engineering Science,2000,55:177-191.
  • 6Tue Johannessen,Sotiris E Prasinis,Hans Livbjerg.Computational analysis of coagulation and coalescence in the flame synthesis of titania particles[J].Powder Technology,2001,118:242-250.
  • 7谢洪勇 宁桂玲 毛中强.火焰CVD法制备TiO2纳米颗粒材料的实验与理论研究[J].过程工程学报,2002,2:183-186.
  • 8LixiWang SiChen HongyongXie.NUMERICAL SIMULATION OF THE GROWTH OF NANOPARTICLES IN A FLAME CVD PROCESS[J].China Particuology,2004,2(5):215-221. 被引量:8

二级参考文献17

  • 1[1]Balabanova,E.(2000).Mechanism of nanoparticles generation by high-temperature methods.Vacuum,58,174-182.
  • 2[2]Fluent Inc.(2002).Fluent:User's Guide (6.0).
  • 3[3]Friedlander,S.K.& Wu,M.K.(1994).Linear rate law for the decay of the excess surface area of a coalescing solid particle.Phys.Rev.B,49,3622-3624.
  • 4[4]Fuchs,N.A.(1964).Mechanics of Aerosols.New York:Pergamon Press.
  • 5[5]Geldat,D.(1986).Gas Fluidization Technology (pp.14-16).John Wiley & Sons Ltd.
  • 6[6]Hidy,G.M.& Brock,J.R.(1965).Some remarks about the coagulation of aerosol particles by Brownian motion.J.Colloid Sci.,20,477-491.
  • 7[7]Johannessen,T.,Pratsinis,S.E.& Livbjerg,H.(2000).Computational fluid-particle dynamics for the flame synthesis of alumina particles.Chem.Eng.Sci.,55,177-191.
  • 8[8]Kobata,A.,Kusakabe,K.& Morroka,S.(1991).Growth and transformation of TiO2 crystallites in aerosol reactor,AlChE J.,37,347-359.
  • 9[9]Koch,W.& Friedlander,S.K.(1990).The effect of particle coalescence on the surface area of a coagulating aerosol.J.Colloid Interface Sci.,140,419-427.
  • 10[10]Kruis,F.E.,Kusters,K.A.,Pratsinis,S.E.& Scarlett,B.(1993).A simple model for the characteristics of aggregate particles undergoing coagulation and sintering.Aerosol Sci.Technol.,19,514-526.

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