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重要传感材料荧光共轭聚合物PPESO_3的一种新的简便合成路线 被引量:8

A Facile Synthetic Route for an Important Sensing Material Fluorescent Conjugated Polymer PPESO_3
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摘要 A facile synthetic route for conjugated polymer PPESO3 was proposed,through which not only the procedure was simplified,but also the dealkylation by BBr3 was avoided,and therefore,the preparing difficulty and danger were greatly reduced,which was obviously beneficial to the preparation and application of(PPESO3).At the same time,the interactions between(PPESO3) and nonionic surfactant(PVP) were investigated.The results indicate that the aggregation of polymer backbone was effectively broken up and the steady complexes consisted of PPESO3 and PVP were formed which would contribute to the preparation of highly sensitive bio-sensors due to the affinity of PVP to biological macromolecules. A facile synthetic route for conjugated polymer PPESO3 was proposed, through which not only the procedure was simplified, but also the dealkylation by BBr3 was avoided, and therefore, the preparing difficulty and danger were greatly reduced, which was obviously beneficial to the preparation and application of PPESO3. At the same time, the interactions between PPESO3 and nonionic surfactant(PVP) were investigated. The results indicate that the aggregation of polymer backbone was effectively broken up and the steady complexes consisted of PPESO3 and PVP were formed which would contribute to the preparation of highly sensitive bio-sensors due to the affinity of PVP to biological macromolecules.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2006年第5期853-855,共3页 Chemical Journal of Chinese Universities
关键词 共轭聚合物 PPESO3 传感器 非离子表面活性剂 聚乙烯吡咯烷酮 Conjugated polymers PPESO3 Sensors Nonionic surfactant PVP
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