焓—熵关系的热力学探讨

A Discussion on the Thermodynamic Relation of Enthalpy-Entropy

用热力学的方法讨论了各种参数变化时焓变与熵变之间的关系,得出焓—熵的补偿关系在一定条件下为线性关系。

The enthalpy -entropy compensation was thermodynamically examined in the phase changes, chemical reactions and other analogous processes. It is clear that there is an intrinsic relation between enthalpy and entropy thermodynamically, but whether the enthalpy - entropy compensation is linear is related to the detail process of the system.