摘要
与氯代烯烃或芳烃相反,氯代膦烯与零价钯的氧化加成反应可以在温和条件下进行.提出了可能的反应机理.起始卤代膦烯的结构决定了反应历程和最终产物的结构.
On the contrary to the vinyl and aryl chlorides, the oxidative addition reaction of zerovalent palladium to chloro-substituted phosphaalkenes proceeded smoothly under mild conditions. The reaction pathway and the structure of final products were found to depend on the structure of starting materials and the mechanism was proposed.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2006年第5期690-693,共4页
Chinese Journal of Organic Chemistry
基金
浙江省留学回国基金(No.008-570506)
宁波大学人才基金(No.008-011013)资助项目.
关键词
卤代膦烯
氧化加成反应
钯化合物
halogen-substituted phosphaalkene
oxidative addition
palladium complex
