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Diastereoselective Epoxidation of N-Enoylsultams with Different Chiral Sultams as Auxiliaries

Diastereoselective Epoxidation of N-Enoylsultams with Different Chiral Sultams as Auxiliaries
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摘要 Asymmetric epoxidation of N-enoylsultams (1, 3-15) incorporating a variety of chiral sultams as the chiral induction elements with UHP/TFAA has been studied. Both diastereomeric isomers of epoxides (2, 16-28) were obtained in high yield and moderate to high optical purity. Asymmetric epoxidation of N-enoylsultams (1, 3-15) incorporating a variety of chiral sultams as the chiral induction elements with UHP/TFAA has been studied. Both diastereomeric isomers of epoxides (2, 16-28) were obtained in high yield and moderate to high optical purity.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2006年第5期681-688,共8页 中国化学(英文版)
关键词 asymmetric epoxidation chiral auxiliary enoylsultam SYNTHESIS asymmetric epoxidation, chiral auxiliary, enoylsultam, synthesis
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