C_(60)和坚牢黑盐K的反应

Synthesis of a Fullerene Azobenzene Derivative

C_(60)常规量制备成功以后,对其反应研究很广.C_(60)分子结构中的 C=C 双健能够发生加成反应,这方面已有很多报道.本文通过 C_(60)和具有偶氮苯骨架的坚牢黑盐 K 的反应,合成了C_(60)的偶氮苯类衍生物.

A fullerene azobenzene derivative was synthesized by the reaction of C_(50)with fast black K salt.The product was isolated by means of silica gel chromatography and identified by field desorption mass spectrometry and ^(13)C NMR spectroscopy,UV spectrometry and IR spectroscopy.Some of theoretical analyses were given.