含酞菁锰光电导功能高分子的合成

SYNTHESIS OF PHOTOCONDUCTIVE FUNCTIONAL POLYMERS BONDED MANGANESE PHTHALOCYANINE

通过重氮盐方法合成含酞菁锰乙烯基咔唑单体，再经自由基共聚合，分别获得了具有光电导性能的含酞菁锰聚合物Ⅰ、Ⅱ、Ⅲ．讨论了采用ＩＲ、ＶＶ／Ｖｉｓ、元素分析、原子吸收等手段对单体和聚合物Ⅰ、Ⅱ、Ⅲ的结构表征，通过荧光光谱分析。

he monomer of vinylcarbazole bonded manganese phthalocyanine (MnPc-VK) was synthesized first by the means of diazo coupling, then photoconductive polymers (Ⅰ). (Ⅱ) and (Ⅲ) containing MnPc were obtained through radical polymerization. The chemical structures of the above monomer and polymers were identified by IR, UV/ Vis, elemental analysis and atomic absorption. Meanwhile, the preliminary studies on their photoconductive mechanism were made through fluorescence analysis.