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MECHANISM AND KINETICS OF TRANSFORMATION OF ALUMINA INCLUSIONS BY CALCIUM TREATMENT 被引量:6

MECHANISM AND KINETICS OF TRANSFORMATION OF ALUMINA INCLUSIONS BY CALCIUM TREATMENT
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摘要 The basic mechanism and kinetics of the transformation process of alumina inclusions in steel was reported when calcium introduced into the steel by wire feeding orpowder injection. To clarify the mechanisms model, experiments were performed by studying reactions between AltOs and CaO in a laboratory furnace and by performing calcium treatments in an 8kg induction furnace for Al deoxidised melt. The phases formed during the reaction between Al2O3 and CaO were examined by SEM-EDS (scanning electron microscope-energy dispersive spectrometer), and the reaction sequence of Al2O3=〉 CA6=〉 CA2 =〉 CA =〉 CAx(l) was discussed in term of the experimental observations. The kinetics of the reaction of calcium with alumina inclusions were simulated by immersing alumina plates in a Ca treated steel melt in the induction furnace. Results were compared with observations of real inclusion transformation. A kinetic model was proposed based on the results. The basic mechanism and kinetics of the transformation process of alumina inclusions in steel was reported when calcium introduced into the steel by wire feeding orpowder injection. To clarify the mechanisms model, experiments were performed by studying reactions between AltOs and CaO in a laboratory furnace and by performing calcium treatments in an 8kg induction furnace for Al deoxidised melt. The phases formed during the reaction between Al2O3 and CaO were examined by SEM-EDS (scanning electron microscope-energy dispersive spectrometer), and the reaction sequence of Al2O3=〉 CA6=〉 CA2 =〉 CA =〉 CAx(l) was discussed in term of the experimental observations. The kinetics of the reaction of calcium with alumina inclusions were simulated by immersing alumina plates in a Ca treated steel melt in the induction furnace. Results were compared with observations of real inclusion transformation. A kinetic model was proposed based on the results.
出处 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2006年第1期1-8,共8页 金属学报(英文版)
关键词 MECHANISM KINETICS ALUMINA INCLUSION transformation mechanism, kinetics, alumina, inclusion, transformation
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  • 1P. Zhang,J. Karwan-Baczewska,S. Du,S. Seetharaman.Application of the high-temperature x-ray diffraction method to the diffusion study in the MgO-AI2O3 system[J].Metallurgical and Materials Transactions A.1996(10)

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