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介孔分子筛的制备与苯加氢反应的催化性能 被引量:2

Synthesis and Catalytic Benzene Hydrogenation of Mesoporous Molecular Sieve
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摘要 Mesoporous molecular sieve (MCM-41) was synthesized by two-step hydrothermal method. The synthesized mesoporous molecular sieve was characterized by XRD, TEM, and specific surface measurement. The resulting mesoporous molecular sieve was well long range ordering and had specific surface area more than 800 m 2 /g. The research on catalytic benzene hydrogenation on MCM-41-supported Pt showed that the conversion of benzene was higher than 95% and the selectivity of cyclohexane was up to 100% at a reaction temperature of 250 ℃ and reaction pressure of 3.0 MPa. Mesoporous molecular sieve (MCM-41) was synthesized by two-step hydrothermal method. The synthesized mesoporous molecular sieve was characterized by XRD, TEM, and specific surface measurement. The resulting mesoporous molecular sieve was well long range ordering and had specific surface area more than 800 m^2/g. The research on catalytic benzene hydrogenation on MCM-41-supported Pt showed that the conversion of benzene was higher than 95% and the selectivity of cyclohexane was up to 100% at a reaction temperature of 250 ℃ and reaction pressure of 3.0 MPa.
出处 《分子催化》 EI CAS CSCD 北大核心 2006年第2期170-172,共3页 Journal of Molecular Catalysis(China)
基金 江苏省教育厅自然科学基金资助(04KJD130040) 江苏大学微纳米中心开放实验室基金资助(1291400001).
关键词 介孔分子筛 合成 表征 苯加氢反应 Mesoporous molecular sieve Synthesis Characterization Benzene hydrogenation
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  • 1姜廷顺,赵谦,陶涛,陆路德,杨绪杰,殷恒波,陈康敏.纳米介孔分子筛的合成、表征与催化性能的研究[J].材料导报,2005,19(12):117-120. 被引量:5
  • 2陈松,许杰,阳永荣,王靖岱,张晓萍,张奎喜.以介孔分子筛为硅源合成的超微β沸石特性及其加氢裂化性能[J].催化学报,2006,27(3):255-258. 被引量:10
  • 3Beck J S,Vartwli J E,Rath W J,et al.A new family of mesoporous molecular sieves prepared with liquid-crystal template mechanism[J].J Am Chem Soc,1992,114 (27):10 834 -10 843.
  • 4Kresge C T,Leonowica M E,Roth W J,et al.Ordered mesoporous molecular synthesized by liquid-crystal template mechanism[J].Nature,1992,359 (6 397):710-718.
  • 5Sayari A,Kruk M.New approaches to pore size engineering of mesoporous silicates[J].Adv Mater,1998,123 (10):1 376 -1 385.
  • 6Branton P J,Dougherty G,Lockhart G,et al.Characterization of porous solids[M].Carmbridge:Royal Society of Chemistry,1997.668.
  • 7Desplantier-Giscard D,Galarneau A,Di Renzo F,et al.15ème réunion du Group Francais des Zé olithes[M].Carry Le Rouet,1999.265.
  • 8Ulagappan N,Rao C N R.Evidence for supramolecules in the process of forming mesoporous silica[J].Chem Commun,1996,56(24):2 759 -2 760.
  • 9Blin J L,Otjacques C,Herrier G,et al.Effects of alkanes on synthesis of MCM-41[J].Stud Surf Sci Catal,2000,129 (1):75-81.
  • 10Blin J L,Otjacques C,Herrier G,et al.Pore size engineering of mesoporous silica using decane as expander[J].Langmuir,2000,16(4):4 229 -4 236.

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