摘要
测定并分析了化合物(Et4_N)_2[Ni_2(SC_6H_4O)_2(μ-SC_6H_4OH)_2]和(Ph_4P)_2[Ni_3(SCH(CH_3)CH_2S)_4]·2CH_3CN的_1H NMR数据,计算了模拟谱,确认它们在DMSO溶液中仍保持原有固体状态的分子结构,它们的抗磁性质得到^(13)C NMR的证实。
1H NMR data of compounds I and II reveal that both compounds are diamagnetic and stable in dimethylsulfoxide solution as thar molecular structures remain the same as those in the solid state. NMR parameters are estimated by comparing the simulated spectra with the observed ones. Diamagnetic properties are confirmed by 13C NMR measurement.
出处
《波谱学杂志》
CAS
CSCD
1990年第2期231-236,共6页
Chinese Journal of Magnetic Resonance
关键词
配位
金属
化合物
化学
NMR谱
NMR
Di-nuclear or tri-nuclear nickel compound
NMR
o-mercaptopbenol
Nickel thiolates
1,2-propanedithiol.
