摘要
综述了烯烃氢甲酰化反应中所应用的膦和亚磷酸酯两大类配体,其研究经历了单磷、双磷及单磷配体再度兴起的过程。列举了一些有代表性的配体及理论。配体研究的发展过程始终围绕着既能提高催化活性又能提高目的产物区域选择性这个主题。
Phosphine ligands and phosphite ligands for hydroformylation of olefin were reviewed, and some representative ligands and theories were summarized.Stages of research progress in phosphorous ligands are monodentate ligands, didentare ligands and monodentate again. Studying ligands is concerned about promoting catalyst activity and regioselectivity.
出处
《上海化工》
CAS
2006年第5期30-34,共5页
Shanghai Chemical Industry
关键词
氧甲酰化
配体
膦亚磷酸酯
烯烃
Hydroformylation
Ligand
Phosphine
Phosphite
Olefin
