摘要
用传统方法合成了新型杂多酸哌啶化合物[(CH2)5NH2]6[P2Mo18O62]·5H2O,并用红外光谱和x-单晶衍射等手段对其进行了表征．结构分析表明,化合物中的多阴离子仍保留其Dawson结构,但其特征振动谱带有一定的红移或蓝移。
A new polyoxometalate, [ （ C H2 ） 5 N H2 ] 6 [ P2 M o18 O62 ]· 5 H2 O has been synthesized using conventional method, and characterized by elemental analysis, IR and single-crystal X-ray diffraction. X-ray analysis shows that the Dawson structure is still reserved in the compound heteropolymolybdata and certain red-shift and blue-shift occur in its characteristic spectral band. It indicates that strong interactions and electrostatic transfer exist between ligand and receptor.
出处
《吉林化工学院学报》
CAS
2006年第2期1-2,共2页
Journal of Jilin Institute of Chemical Technology
基金
国家自然科学基金资助项目(20371012)
