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Synthesis and Fluorescence Properties of Eu ^(2+)-Doped KMgF_3 Nanoparticles 被引量:1

Synthesis and Fluorescence Properties of Eu ^(2+)-Doped KMgF_3 Nanoparticles
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摘要 The phase diagram of a cetyltrimethyl ammonium bromide (CTAB)/n-butanol/n-octane/KNO3-Mg( NO3)2 system was drawn. Nanoparticles of Eu^2+ -doped KMgF3 were prepared from the quaternary microemulsions of cetyltrimethyl ammonium bromide( CTAB), a-butanol, n-octane and water. The X-ray diffraction(XRD) patterns were indexed to a pure KMgF3 cubic phase. The environmental scanning electron microscopic(ESEM) images show the presence of spherical Eu^2+ -doped KMgF3 nanoparticles with a diameter of ca. 20 nm. The emission of KMgF3: Eu^2+ nanoparticles peaks at 360 nm. The excitation band was observed at 250 nm with a blue shift of ca. 70 nm compared with that of KMgF3: Eu^2+ single crystal. The preparation method of nano-KMgF3: Eu^2+/PMMA composite films was inquired into. The phase diagram of a cetyltrimethyl ammonium bromide (CTAB)/n-butanol/n-octane/KNO3-Mg( NO3)2 system was drawn. Nanoparticles of Eu^2+ -doped KMgF3 were prepared from the quaternary microemulsions of cetyltrimethyl ammonium bromide( CTAB), a-butanol, n-octane and water. The X-ray diffraction(XRD) patterns were indexed to a pure KMgF3 cubic phase. The environmental scanning electron microscopic(ESEM) images show the presence of spherical Eu^2+ -doped KMgF3 nanoparticles with a diameter of ca. 20 nm. The emission of KMgF3: Eu^2+ nanoparticles peaks at 360 nm. The excitation band was observed at 250 nm with a blue shift of ca. 70 nm compared with that of KMgF3: Eu^2+ single crystal. The preparation method of nano-KMgF3: Eu^2+/PMMA composite films was inquired into.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2006年第3期274-277,共4页 高等学校化学研究(英文版)
基金 SupportedbytheNationalNaturalScienceFoundationofChina(No.90201032)andtheScienceandTechnologyDepartmentofJilinProvince(No.20050507).
关键词 FLUORIDE Microemulsion phase diagram NANOSTRUCTURE X-ray diffraction LUMINESCENCE Fluoride Microemulsion phase diagram Nanostructure X-ray diffraction Luminescence
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