摘要
综述酮烯醇盐氧化二聚反应的规律,重点是立体选择性的过程;近期进展是利用手性辅助试剂,不对称合成链状和环状的1,4-二羰基化合物。
This review summarizes the state of the art of the coupling of the enolate of ketones, focusing on the stereoselectivity of the process. Recent developments making use of chiral auxiliaries have put forward the versatility of procedure for the asymmetric synthesis of linear and cyclic 1,4-dicarbonyl compounds.
出处
《江苏技术师范学院学报》
2006年第2期13-16,共4页
Journal of Jiangsu Teachers University of Technology
关键词
酮
烯醇盐
立体选择性
氧化二聚反应
ketones
enolate
stereoselectivity
oxidative dimerization
