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多元校正-速差动力学分光光度法同时测定三组分有机磷农药 被引量:2

Simultaneous Kinetic-spectrophotometric Determination of Three Organophosphorus Pesticides with Multivariate Calibration Methods
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摘要 A kinetic-spectrophotometric method for the determination of parathion,methyl-parathion and fenitrothion was developed.It was based on the kinetic reaction of these compounds with H2O2 in alkaline medium.Under the optimal conditions,quantitative analysis for each compound in mixtures was investigated with the aid of multivariate calibration methods.The proposed method was applied to several water samples spiked with known amounts of the pesticides with satisfactory results. A kinetic-spectrophotometric method for the determination of parathion, methyl-parathion and fenitrothion was developed. It was based on the kinetic reaction of these compounds with H2O2 in alkaline medium. Under the optimal conditions, quantitative analysis for each compound in mixtures was investigated with the aid of multivariate calibration methods. The proposed method was applied to several water samples spiked with known amounts of the pesticides with satisfactory results.
机构地区 南昌大学化学系
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2006年第6期1048-1050,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金(批准号:20365001 20562009)资助
关键词 动力学 多元校正 对硫磷 甲基对硫磷 杀螟硫磷 Kinetics Multivariate calibration Parathion Methyl-parathion Fenitrothion
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