摘要
The title complex has been synthesized by the reaction of silicotungstic acid, 1,10-phenanthroline (phen) monohydrate and cupric acetate. The crystal structure belongs to triclinic system, space group P1 with a=1.158 46(15) nm, b=1.658 8(2) nm, c=1.664 4(2) nm, α=82.090(2)°, β=76.001(2)°, γ=86.531(2)°, and V=3.072 6(7) nm3, Dc=3.887 g·cm-3, Z=2, F(000)=3 196. R1=0.086 7, wR2=0.185 8. The structure shows that the copper?髤 atom is coordinated with two nitrogen atoms from the one phen and three oxgygen atoms from three water, forming a distorted square-pyramid configuration The cyclic voltametric behavior of the complex is also reported. CCDC: 298807.
The title complex has been synthesized by the reaction of silicotungstic acid, 1,10-phenanthroline （phen） monohydrate and cupric acetate. The crystal structure belongs to triclinic system, space group P1^- with a= 1.158 46（15） nm, b = 1.658 8（2） nm, c= 1.664 4（2） nm, α=82.090（2）°,β=76.001（2）°, γ=86.531（2）°, and V=3.072 6（7） nm^3, Dc=3.887 g·cm^-3, Z=2, F（000）=3 196. R1=0.086 7, wR2=0.185 8. The structure shows that the copper（Ⅱ） atom is coordinated with two nitrogen atoms from the one phen and three oxgygen atoms from three water, forming a distorted square-pyramid configuration The cyclic voltametric behavior of the complex is also reported. CCDC： 298807.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第6期1072-1076,共5页
Chinese Journal of Inorganic Chemistry
基金
教育部高校骨干教师基金资助项目(No.2000K52141)
湖南省教育厅一般项目(No.05c001)
衡阳师范学院青年项目(No.2003C16)。
关键词
铜(Ⅱ)配合物
钨硅酸
晶体结构
电化学性质
copper（Ⅱ） complex
silicotungstic acid
crystal structure
electrochemical property
