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Extraction of Neodymium by Emulsion-Liquid-Membrane within Hollow-Fiber-contactor and Its Mass Transfer Properties

Extraction of Neodymium by Emulsion-Liquid-Membrane within Hollow-Fiber-contactor and Its Mass Transfer Properties
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摘要 A non-dispersive extraction technique, using an emulsion liquid membrane within a hollow-fiber-contactor for the extraction and enrichment of Nd^3+ from the dilute feed aqueous, was applied. The emulsion system is consisted of span80 [ sorbitian monooleate], paraffin oil, D2EHPA [ 2-( 2-ethylhexyl- phosphonic acid)], kerosene as well as HCl solution. The extraction under various conditions such as the span80 concentrations, the flow rate of aqueous, the extraction time and HCl concentrations in receiving phase were studied. Results show that the lower the flow rates of aqueous are, the higher the extraction percentage and enrichment-fold are, and the extraction percentage increases with the increasing of HCl concentrations. When the initial Nd^3+ concentration in feed is maintained at 1000 mg· L^-1 and the emulsion is recycled with 70 times by a counter-flow, A non-dispersive extraction technique, using an emulsion liquid membrane within a hollow-fiber-contactor for the extraction and enrichment of Nd^3+ from the dilute feed aqueous, was applied. The emulsion system is consisted of span80 [ sorbitian monooleate], paraffin oil, D2EHPA [ 2-( 2-ethylhexyl- phosphonic acid)], kerosene as well as HCl solution. The extraction under various conditions such as the span80 concentrations, the flow rate of aqueous, the extraction time and HCl concentrations in receiving phase were studied. Results show that the lower the flow rates of aqueous are, the higher the extraction percentage and enrichment-fold are, and the extraction percentage increases with the increasing of HCl concentrations. When the initial Nd^3+ concentration in feed is maintained at 1000 mg· L^-1 and the emulsion is recycled with 70 times by a counter-flow,
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第3期280-280,共1页 稀土学报(英文版)
关键词 emulsion liquid membrane hollow-fiber-membrane non-dispersive extraction mass-transfer coefficient NEODYMIUM rare earths emulsion liquid membrane hollow-fiber-membrane non-dispersive extraction mass-transfer coefficient neodymium rare earths
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