摘要
报道了对氯苯胺与丙烯腈在AlCl3的催化下发生加成反应合成标题化合物,其合适的反应条件是:AlCl3的用量为对氯苯胺的40%(物质的量比),反应温度为78~90℃,反应时间16h。其结果表明,AlCl3对该反应具有很高的催化效率,产物收率达89%。
In this paper, a synthesis of p-chloro-N, N-bis(2-cyanoethyl)aniline was reported by using p-chloroaniline, acrylonitrile and AlCl3, the experimental result had proved that AlCl3 was an excellent catalyst, while the AlCl3 was 40% (mol) of p-chloroaniline, the temperature were 78~90℃, the time 16 hours, the yield of p-chloro-N, N-bis (2-cyanoethyl) aniline were over 89%.
出处
《化学试剂》
CAS
CSCD
北大核心
2006年第5期267-268,273,共3页
Chemical Reagents
基金
湖南省教育厅科研基金项目(03C562)
中南林学院青年基金项目(04027B)。