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Reduction of Azide to Amine Using Fe/AlCl3 or Fe/BiCl3 System in Aqueous EtOH

Reduction of Azide to Amine Using Fe/AlCl3 or Fe/BiCl3 System in Aqueous EtOH
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摘要 Azides were reduced to the corresponding amines by two new metal/Lewis acid systems in aqueous EtOH with yields ranging from 80% to 95%. The new reduction systems were Fe/AlCl3·6H2O or Fe/BiCl3 system in H2O/ethanol (2 : 1, Ⅴ :Ⅴ) at room temperature. Fifteen azides with different functional groups were well reduced to the corresponding amines in excellent yields. Azides were reduced to the corresponding amines by two new metal/Lewis acid systems in aqueous EtOH with yields ranging from 80% to 95%. The new reduction systems were Fe/AlCl3·6H2O or Fe/BiCl3 system in H2O/ethanol (2 : 1, Ⅴ :Ⅴ) at room temperature. Fifteen azides with different functional groups were well reduced to the corresponding amines in excellent yields.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2006年第6期825-826,共2页 中国化学(英文版)
关键词 AZIDE REDUCTION AMINE AMIDE azide, reduction, amine, amide
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