富勒烯材料的催化作用研究进展

Advances in Catalytic Function of Fullerene Materials

介绍了富勒烯材料(富勒烯和富勒烯衍生物)的催化作用研究进展,特别是催化有机反应方面,包括催化氢转移和硅氢化反应、烷烃裂解反应、氢氘互换反应、耦合和烷基转移反应等。这种新材料还可以催化产生单线态氧(1O2)的化学反应、催化非金属固氮反应、催化石墨合成金刚石的反应,同时还可催化高能燃料的燃烧过程,具有广泛的应用前景。

The applications of fullerene materials （including fullerenes and fuUerene-based materials） in catalytic reactions, especially in organic reactions, including application in hydrogen transfer and hydrosilylation, pyrolysis of alkanes, H2-D2 exchange, coupling and alkyl transfer reaction are reviewed in this paper. Singlet oxygen reaction, nonmetal nitrogen-fixation reaction, processes could be also catalyzed graphite-diamond phase transition process and high-energy materials combustion by these new materials. All reactions showed very good catalytic functionality.