摘要
研究甲壳胺（CTS）对甲基丙烯酸（MAA）水溶液聚合的影响，探讨在不同MAA／－NH2摩尔比的水溶液中MAA聚合形成聚合物的分子量和结构规整性，结果表明CTS对MAA聚合物的结构规整性有影响，即具有一定的“模板”效应。
In this paper, we study the effect of the macromolecular chain of chitosan (CTS) on the polymerization of methylacrylic acid (MAA) in aqueous solution.The molecular weight and tacticity of the polymer obtained from radical polymerization of MAA in aqueous sdlutins with different MAA/-NH2 molar ratios are also studied. The result demonstrates that CTS has some matrix effect (or macromolecular effect) on the tacticity of the polymer of MAA.
基金
国家自然科学基金!29170184
关键词
甲壳胺
甲基丙烯酸
溶液聚合
模板效应
chitosan
methacyrlic acid
polymethyl methacrylate
matrix effect
