N，N-二取代-α-羰基硫代甲酰取代胺的合成研究

Synthesis ofα-carbonyl-N, N-disubstitued thioformamides

以取代苯乙酮为原料,首次得到了反应中间体二-(1,1-二氯-1-芳酰基)三硫醚,对其进行了红外、核磁、质谱和X-衍射分析,并且用该化合物与仲胺反应得到了六个α-羰基硫代甲酰取代胺。

Acetophenone and its derivatives reacted with thionyl chloride to afford bis （1,1-dichloro-1-aroyl） trisulfides, followed by reacting with the secondary amines to give a-earbonyl-N, N-disubstitued thioformamides. The structures of all compounds were confirmed by IR,NMR,MS spectra, furthermore, the structure of bis （1,1-dichloro-l-benzoyl） trisulfide was analyzed by X-ray diffraction method.