摘要
A novel supramolecular polymolybdic（VI） acid was unexpectedly synthesized by the reaction of sodium molybdate with 1,2,4,5-benzenetetracarboxylic and trichloroacetic acids in 1：1：1 molar ratio under hydrothermal condition. The crystal belongs to tetragonal with space group P4/mbm, a = 0.88867（17）, b = 0.88867（17）, c = 0.55676（15） nm, Z = 3, V = 0.43969（17） nm^3, Dc = 4.486 g/cm^3,μ = 4.365 mm^-1, F（000） = 576, R = 0.0273 and wR = 0.0679. In the crystal, the Mo（VI） atoms are six- and five-coordinated in distorted octahedral and trigonal bipyramidal geometries, respectively. Furthermore, these Mo（VI） atoms, bearing different coordinated environments, are bridged by OH groups with disorder O atoms to form a twodimensional framework with pentagonal grids. It is worthy of notice that these adjacent twodimensional frameworks are extended into a three-dimensional supramolecular array with pentagonal large cavities＇by Van Der Waals＇ forces and hydrogen bonding interactions.
A novel supramolecular polymolybdic（VI） acid was unexpectedly synthesized by the reaction of sodium molybdate with 1,2,4,5-benzenetetracarboxylic and trichloroacetic acids in 1：1：1 molar ratio under hydrothermal condition. The crystal belongs to tetragonal with space group P4/mbm, a = 0.88867（17）, b = 0.88867（17）, c = 0.55676（15） nm, Z = 3, V = 0.43969（17） nm^3, Dc = 4.486 g/cm^3,μ = 4.365 mm^-1, F（000） = 576, R = 0.0273 and wR = 0.0679. In the crystal, the Mo（VI） atoms are six- and five-coordinated in distorted octahedral and trigonal bipyramidal geometries, respectively. Furthermore, these Mo（VI） atoms, bearing different coordinated environments, are bridged by OH groups with disorder O atoms to form a twodimensional framework with pentagonal grids. It is worthy of notice that these adjacent twodimensional frameworks are extended into a three-dimensional supramolecular array with pentagonal large cavities＇by Van Der Waals＇ forces and hydrogen bonding interactions.
基金
This work was supported by the National Natural Science Foundation of China (No. 20571057)
