摘要
α-重氮苯乙酸酯与N-(苯乙烯基)-吗啉在铜盐催化下的反应,能够以高的化学产率制备手性γ-酮酯。详细讨论了γ-酮酯的制备方法、烯胺的结构对反应的影响。
Reaction of methyl phenyldiazoacetates with N - ( 1 - styryl) morpholine catalyzed by copper salt was studied and the yield of chiraγ - keto ester was high. Preparation of γ - keto ester and effect of enamines on the reaction was also investigated.
出处
《云南化工》
CAS
2006年第3期11-13,共3页
Yunnan Chemical Technology
基金
江苏省重点实验室开放基金(S8109104)