［NaXY」_2W_nMo_（6－n）O_（19）的~1HNMR和IR研究

￣1H NMR AND IR STUDIES OF [NaXY]_2W_nMo_(6-n)O_(19)

本文对二种具有新奇结构的［ＮａＸＹ］２ＷｎＭｏ６－ｎＯ１９（Ⅰ．Ｘ＝ＤＢ１８Ｃ６，Ｙ＝ＣＨ３ＯＨ，ｎ＝４；Ⅱ．Ｘ＝ＤＢ２４Ｃ８，ｎ＝１）冠醚钼钨杂多酸超分子配合物进行了核磁共振和红外光谱测定，判定了谱图的归属并考察了结构与谱学参数之间的关系。

Two new complexes of [NaXY]2WnMo(6-n)O(19)(Ⅰ: X=DB18C6, Y=CH3OH , n = 4;Ⅱ: X=DB24CS, n=1 ) have novel structrures. In this paper their 1H NMR and IR spectrahave been determined and the relation of structure with 1H NMR and IR parameters havebeen studied.