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阳极氧化水解法制备TIO_2纳米膜 被引量:5

Preparation of Nanometer TiO_2 Films by Anodic Oxidative Hydrolysis
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摘要 Ti(IV) oxide has been an important semi-conductor material in photoelectrochemical cell, especially in the area of developing photochemical nanocrystalline solar cell.The TiO2 films were deposited on SnO2 (F-doped) glass electrodes by anodic oxidative hydrolysis of acidic aqueous TiCl3 solutions. The films are uniform in thickness, have an average size of approximately 20nm, and have the anatase structure after annealing at 450℃. The method of anodic oxidative hydrolysis, the method of electrodepositing high pure TiO2 (anatase) on transparent conducting oxide (TCO) glass, condition of producing TiO2 film, and some character of the film have also bcen investigated. Ti(IV) oxide has been an important semi-conductor material in photoelectrochemical cell, especially in the area of developing photochemical nanocrystalline solar cell.The TiO2 films were deposited on SnO2 (F-doped) glass electrodes by anodic oxidative hydrolysis of acidic aqueous TiCl3 solutions. The films are uniform in thickness, have an average size of approximately 20nm, and have the anatase structure after annealing at 450℃. The method of anodic oxidative hydrolysis, the method of electrodepositing high pure TiO2 (anatase) on transparent conducting oxide (TCO) glass, condition of producing TiO2 film, and some character of the film have also bcen investigated.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1996年第8期758-760,共3页 Acta Physico-Chimica Sinica
基金 中国科学院院长重点基金 "化学太阳能光电池"资助
关键词 阳极氧化 水解 纳米晶体 太阳能电池 氧化钛 Anodic oxidative, Hydrolysis, Nanocrystalline, Solar cell
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