摘要
研究了芳烃用Ce(Ⅲ)/Ce(Ⅵ)及Ag(Ⅰ)/Ag(Ⅱ)双媒质体系的间接电氧化。讨论了电流密度恒定时Ag(Ⅰ)浓度对生成Ce(Ⅵ)电流效率的影响。实验结果表明,芳烃氧化选择性强,电流效率高。
The indirect electrical oxidation of aromatic hydrocarbons by using Ce (Ⅲ)/Ce (Ⅵ)and Ag(I)/Ag(Ⅱ)double mediated systems was investigated.The effects of silver ion concentration on the current efficiency were discussed at various current densities.The experimental results showed that aromatic hydrocarbons can be oxidized with higher selectivity and higher current efficiency.
出处
《化学试剂》
CAS
CSCD
北大核心
1996年第4期243-244,210,共3页
Chemical Reagents
关键词
芳烃
氧化
电流效率
电流密度
双媒质体系
铈
银
aromatic hydrocarbons,oxidation,current efficiency,current density,double mediated syntem