摘要
乙酰基二茂铁与三甲基腈硅烷反应制得α-氰基-α-二茂铁基乙氧三甲硅烷，经四氢铝锂还原后得到2-羟基-2-二茂铁基丙胺（FcA），用该氨基醇分别与氯化镍，氯化铜，氯化锌，氯化镉，氯化汞反应，制备了氨基醇-镍（Ⅱ）、氨基醇-铜（Ⅱ）、氨基醇-锌（Ⅱ）、氨基醇—镉（Ⅱ）、氨基醇-汞（Ⅱ）五种二茂铁基氨基醇-重金属配合物（用通式M-FcA表示）。用Nexus670FTIR红外光谱仪对二茂铁基氨基醇和五种配合物在4000-400cm^-1范围内测定傅里叶变换红外光谱，对各M-FcA的FTIR主要吸收峰做了经验归属，并将各M-FcA的特征吸收峰与FcA的相应吸收峰作对比分析，结果表明：配合物中-OH，-NH2键的吸收峰位置均向低波数方向移动；C-O，C-N键吸收峰位置向高波数方向移动。说明二茂铁基氨基醇中的氨基、羟基与重金属离子之间形成了配位键。
α-cyano-α-ferrocenylethoxytrimethylsilame was prepared by the addition of trimethysilyl cyanide to acetylferrocene.2-Hydroxy-2-ferrocenylpropylamine（FcA） was synthesized by the reduction of α-cyano-α-ferrocenylethoxytrimethylsilame with lithium aluminum hydride. A series of coordinate complexes-FcA-Ni（ Ⅱ ）, FcA-Cu（ Ⅱ ）, FcA-Zn（ Ⅱ ）, FcA-Cd（ Ⅱ ） and FcA- Hg（ Ⅱ ） were obtained through coordination of this ligand with MCl2 （M=Ni, Cu, Zn, CA and Hg）. The FTIR spectra of the complexes and ligand were obtained in the range of 4 000-400 cm^-1. Their major bands were assigned and compared. The results showed that in all complexes some bands（υO-H, υN-H, δO-H, δN-N） were shifted to lower wave number, and some（υC-N, υO-N） were shifted to higher wave number. The aminoalcohol groups and metal ions were bound with coordinated bond.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
2006年第6期1054-1056,共3页
Spectroscopy and Spectral Analysis
基金
国家自然科学基金(20062004)
内蒙古师范大学青年基金(QN00102)资助项目
