摘要
由简历油,石油,和 CH <SUB>4</SUB> 改过的催化蒸气的氢生产在新奇做金属的催化剂上被调查(Ca <SUB>24</SUB > 艾尔 <SUB>28</SUB > O <SUB>64</SUB>)<SUP>4+</SUP>4O<SUP></SUP>/Mg (C12A7-Mg ) 。改过的催化蒸气从 250 ~ 850 瑡癩?瑳畲瑣牵 e
Hydrogen production by catalytic steam reforming of the bio-oil, naphtha, and CH4 was investigated over a novel metal-doped catalyst of (Ca24Al28O64)^4+·4O^-/Mg (C12A7-Mg). The catalytic steam reforming was investigated from 250 to 850℃ in the fixed-bed continuous flow reactor. For the reforming of bio-oil, the yield of hydrogen of 80% was obtained at 750℃, and the maximum carbon conversion is nearly close to 95% under the optimum steam reforming condition. For the reforming of naphtha and CH4, the hydrogen yield and carbon conversion are lower than that of bio-oil at the same temperature. The characteristics of catalyst were also investigated by XPS. The catalyst deactivation was mainly caused by the deposition of carbon in the catalytic steam reforming process.