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Preparation of fine copper powders and their application in BME-MLCC 被引量:6

Preparation of fine copper powders and their application in BME-MLCC
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摘要 The preparation of fine copper powders by chemical reduction method was investigated. The reaction of [Cu(NH3)4]2^+ complex with hydrazine hydrate gives spherical monodispersed fine copper powders. The spherical copper powder with a uniform size of 3.5 ± 0.5 μtm was processed to obtain flake copper powder having a uniform size of 8-10 μm, excellent dispersibility and uniform shape. The spherical copper powder of 2.5 ±0.3 μm in size, flake copper, glass frit and vehicle were mixed to prepare copper paste, which was fired in 910-920℃ to obtain BME-MLCC (base metal multilayer ceramic capacitor) with a dense surface of end termination, high adhesion and qualified electrical behavior. Polarized light photo and SEM were employed to observe the copper end termination of BME-MLCC. The rough interface from the interracial reaction between glass and chip gives high adhesion. The preparation of fine copper powders by chemical reduction method was investigated. The reaction of [Cu(NH3)4]2^+ complex with hydrazine hydrate gives spherical monodispersed fine copper powders. The spherical copper powder with a uniform size of 3.5 ± 0.5 μtm was processed to obtain flake copper powder having a uniform size of 8-10 μm, excellent dispersibility and uniform shape. The spherical copper powder of 2.5 ±0.3 μm in size, flake copper, glass frit and vehicle were mixed to prepare copper paste, which was fired in 910-920℃ to obtain BME-MLCC (base metal multilayer ceramic capacitor) with a dense surface of end termination, high adhesion and qualified electrical behavior. Polarized light photo and SEM were employed to observe the copper end termination of BME-MLCC. The rough interface from the interracial reaction between glass and chip gives high adhesion.
机构地区 College of Chemistry
出处 《Journal of University of Science and Technology Beijing》 CSCD 2006年第3期250-255,共6页 北京科技大学学报(英文版)
关键词 spherical copper powder flake copper powder chemical reduction BME-MLCC spherical copper powder flake copper powder chemical reduction BME-MLCC
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  • 1Arvind Sinha,Swapan Kumar Das,T. V. Vijaya Kumar,V. Rao,P. Ramachandrarao.Synthesis of Nanosized Copper Powder by an Aqueous Route[J].Journal of Materials Synthesis and Processing.1999(6)
  • 2R. Sarraf-mamoory,G. P. Demopoulos,R. A. L. Drew.Preparation of fine copper powders from organic media by reaction with hydrogen under pressure: Part I. Experimental study[J].Metallurgical and Materials Transactions B.1996(4)
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