摘要
An in-situ and nondestructive technique was proposed and established for the study of domain switching in PLZT ceramics via observation of Raman spectrum changes based on the Raman light scattering principle and the soft mode theory. A Vickers indent was introduced into the polarized PLZT specimen so that the Raman spectrum change associated with the domain switching as induced either by an applied electric field or by a stress field surrounding the tip of the Vickers indent crack was in-situ measured and studied using this established technique. The relation between the domain switching and the measured Raman spectrum was discussed. It is well demonstrated that this technique can sensitively detect and measure the domain switching via the observation of Raman spectrum changes. The results confirm that Raman spectrum intensity is directly attributed to the change of the polarization direction of the incidence and scattered lights with respect to the direction of the average polarization direction of the domain in the polarized specimen. When the two directions are parallel, the induced polarizability tensor of the specimen would be enhanced and give rise to a higher intensity for Raman scattering light.
An in-situ and nondestructive technique was proposed and established for the study of domain switching in PLZT ceramics via observation of Raman spectrum changes based on the Raman light scattering principle and the soft mode theory. A Vickers indent was introduced into the polarized PLZT specimen so that the Raman spectrum change associated with the domain switching as induced either by an applied electric field or by a stress field surrounding the tip of the Vickers indent crack was in-situ measured and studied using this established technique. The relation between the domain switching and the measured Raman spectrum was discussed. It is well demonstrated that this technique can sensitively detect and measure the domain switching via the observation of Raman spectrum changes. The results confirm that Raman spectrum intensity is directly attributed to the change of the polarization direction of the incidence and scattered lights with respect to the direction of the average polarization direction of the domain in the polarized specimen. When the two directions are parallel, the induced polarizability tensor of the specimen would be enhanced and give rise to a higher intensity for Raman scattering light.
出处
《中国有色金属学会会刊:英文版》
EI
CSCD
2006年第3期638-642,共5页
Transactions of Nonferrous Metals Society of China
基金
Project(10472098) supported by the National Natural Science Foundation of China
关键词
铁电陶瓷
维氏硬度计
域转换
拉曼光谱
PLZT
ferroelectric ceramics
Vickers indent
domain switching
Raman observation