配位聚合物[Cu_2(SCN)_2(μ-pym)]_∞的合成和光谱性能研究

Synthesis and Spectrum Performance Research of [Cu_2(SCN)_2(μ-pym)]_∞

由Cu(I)化合物与嘧啶(pym)反应,成功地合成了由pym桥联而成的配位聚合物[Cu2(SCN)2(μ-pym)]∞。对配合物进行了元素分析、X射线衍射等表征,以及红外光谱、紫外光谱、荧光光谱等光谱性质的研究。

A novel Cu （Ⅰ） complex [Cu2（SCN）2（μ-pym）]∞ containing N - donor heterocycles pyrimidine （pym） was synthesized. The complex was characterized by elementary analysis, infrared spectroscopic analysis, visible spectroscopic analysis, luminescence spectroscopic analysis and X - ray single crystal diffraction.