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Synthesis and Crystal Structure of 2-Nitrophenyl N,N-Bis(2-chloroethyl)-N'-(4-methylbenzene- sulfonamino)ethyl-phosphorodiamidate

Synthesis and Crystal Structure of 2-Nitrophenyl N,N-Bis(2-chloroethyl)-N'-(4-methylbenzene- sulfonamino)ethyl-phosphorodiamidate
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摘要 The crystal structure of 2-nitrophenyl N,N-bis(2-chloroethyl)-N'-(4-methylbenzene-sulfonamino)ethyl-phosphorodiamidate (C19H25Cl2N4O6PS) was determined by single-crystal X-ray diffraction analysis. The compound crystallizes in the triclinic system, space group PI^- with a = 9.3664(13), b = 9.9560(14), c = 13.1803(18) ,A, α = 87.338(2), β= 87.632(2), γ = 79.536(2)°, Dc = 1.484 g/cm^3, Z = 2, λ = 0.71073 A, μ(MoKα) = 0.465, Mr = 539.36, V = 1206.7(3) A^3, F(000) = 560, the final R = 0.0426 and wR = 0.1097 for 3463 observed reflections with I 〉 2σ(I). The crystal structure of 2-nitrophenyl N,N-bis(2-chloroethyl)-N'-(4-methylbenzene-sulfonamino)ethyl-phosphorodiamidate (C19H25Cl2N4O6PS) was determined by single-crystal X-ray diffraction analysis. The compound crystallizes in the triclinic system, space group PI^- with a = 9.3664(13), b = 9.9560(14), c = 13.1803(18) ,A, α = 87.338(2), β= 87.632(2), γ = 79.536(2)°, Dc = 1.484 g/cm^3, Z = 2, λ = 0.71073 A, μ(MoKα) = 0.465, Mr = 539.36, V = 1206.7(3) A^3, F(000) = 560, the final R = 0.0426 and wR = 0.1097 for 3463 observed reflections with I 〉 2σ(I).
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第7期797-800,共4页 结构化学(英文)
基金 Corresponding author. Chen Ru-Yu, born in 1919, professor, member of the Chinese Academy of Sciences,
关键词 SULFONAMIDE crystal structure phosphorodiamidate sulfonamide, crystal structure, phosphorodiamidate
分类号 O [理学]
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