摘要
The title compound [ Mn5 （ H2PO4 ）2 （ PO4 ）2 （ H20）4 ] was hydrothermally synthesized in the presence of calix[4]arene-p-tetrasulfonate. The title compound was structurally characterized by X-ray single crystal diffraction. It crystallizes in the monoclinic space group C2/c with α = 1.762 9（4） nm, b = 0.913 44（18） nm, c=0.94977（19） nm, β=96.52（3）°, V=1.5195（5） nm^3, Z=4 and R1=0.0283, and exhibits a three-dimensional framework and channel structure. It was proposed that calixarene can act as template during the formation of the title compound because calixarene can bind Mn^2＋ through second-sphere coordination.
The title compound [ Mn5 （ H2PO4 ）2 （ PO4 ）2 （ H20）4 ] was hydrothermally synthesized in the presence of calix[4]arene-p-tetrasulfonate. The title compound was structurally characterized by X-ray single crystal diffraction. It crystallizes in the monoclinic space group C2/c with α = 1.762 9（4） nm, b = 0.913 44（18） nm, c=0.94977（19） nm, β=96.52（3）°, V=1.5195（5） nm^3, Z=4 and R1=0.0283, and exhibits a three-dimensional framework and channel structure. It was proposed that calixarene can act as template during the formation of the title compound because calixarene can bind Mn^2＋ through second-sphere coordination.
基金
Sponsored bythe National Natural Science Foundation of China (20271007)
Specialized Research Fund for the Doctoral Program of HigherEducation (20030007014)
