摘要
A new one-dimensional compound [Cd(dafo)(SCN)2]n (dafo=4,5-diazafluoren-9-one) has been synthesized and characterized by single crystal X-ray diffraction. It crystallizes in the orthorhombic system; space group Pbca with a=1.708 6(5), b=1.303 6(4), c=2.592 6(8) nm, V=5.775(3) nm3, and Z=16. The crystal structure revealed that the structure of [Cd(dafo)(SCN)2]n features μ-1,3-thiocyante bridges and 1D chains. It consists of octahedrally coordinated Cd atoms. Both Cd(1) and Cd(2) are surrounded by two nitrogen atoms from dafo, two S atoms and two N atoms from two di-μ-1,3 thiocyanato bridges. CCDC: 251185.
A new one-dimensional compound [Cd（dafo）（SCN）2]n（dafo=4,5-diazafluoren-9-one） has been synthesized and characterized by single crystal X-ray diffraction. It crystallizes in the orthorhombic system; space group Pbca with a=1.708 6（5）, b=1.303 6（4）, c=2.592 6（8） nm, V=5.775（3） nm^3, and Z=16. The crystal structure revealed that the structure of [Cd（dafo）（SCN）2]. features μ-1,3-thiocyante bridges and 1D chains. It consists of octahedrally coordinated Cd atoms. Both Cd（1） and Cd（2） are surrounded by two nitrogen atoms from dafo, two S atoms and two N atoms from two di-μ-1,3 thiocyanato bridges. CCDC： 251185.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第7期1285-1288,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20361004)
云南省自然科学基金资助项目(No.2003E0012M,2003RC13和2004E0008M)
关键词
cd(Ⅱ)
晶体结构
dafo
SCN-桥联
cadmium（Ⅱ）
crystal structure
4,5-diazafluoren-9-one
thiocyanato bridging
