疏水缔合水溶性聚合物聚合方法的研究进展

Progress on Research for Preparation of Water-Soluble Hydrophobic Associating Polymer

对制备疏水缔合水溶性聚合物的聚合方法进行了综述,包括非均相共溶剂法、均相共溶剂法、超声波法、胶束共聚法、微乳液聚合法、反相微乳液聚合法、自由基界面聚合法、无皂乳液聚合法、活性阴离子聚合法、基团转移聚合法、原子转移自由基聚合法、可逆加成-断裂链转移聚合法、氧阴离子引发聚合法、高分子化学修饰法、二氧化硫环聚合反应法、超临界二氧化碳法等。评述了各种聚合方法制备疏水缔合水溶性聚合物的特点,认为微乳液聚合法和超临界二氧化碳法具有较好的应用前景。

Progress of polymerization methods for preparation of water-soluble hydrophobic associating polymer was reviewed, namely heterogeneous mutual solvent polymerization, homogeneous mutual solvent polymerization, ultrasonicwave polymerization, micellar copolymerization, microemulsion polymerization, inverse microemultion polymerization, free-radical interface polymerization, soap-free emulsion polymerization, living anion polymerization, group transfer polymerization, atom transfer free radical polymerization, reversible addition and fragmentation chain tranfer polymerization, oxyanioninitiated polymerization, macromonomer polymerization techniques, cyclocopolymerization of sulfur dioxide and polymerization in supercritical carbon dioxide. Characteristics of the polymers were also mentioned. Microemulsion polymerization and polymerization in supercritical carbon dioxide would be good in application perspective.