1,6-二(2-羟基-5-辛基苯基)-己二酮的合成

Synthesis of 1,6-Di-(2-hydroxyl-5-octylphenyl)-hexanedione

以二羧酸和辛基酚为原料,无水三氯化铝为催化剂,经取代反应、酰基化反应和Fries重排反应合成了可连接不同活性基团的Gemini表面活性剂中间体1,6-二-(2-羟基-5-辛基苯基)-己二酮。其结构经1H NMR,IR和MS表征。

A kind of Gemini surfactant, 1,6-di-（2-hydroxyl-5-octylphenyl） -hexanedione, was synthesized from dicarboxylic acid and octyl phenol using anhydrous aluminium trichloride as a catalyst. The structure was characterized by 1^ H NMR, IR and MS.