聚碳硅烷制备连续SiC纤维的不熔化处理工艺研究进展

Research Development of Curing Treatment of Polycarbosilane to Prepare Continuous SiC Fibre

综述了先驱体转化法制备SiC纤维过程中聚碳硅烷(PCS)的各种不熔化处理方式及其发展状况。通过不熔化方式对终烧产物SiC纤维性能的比较,讨论了各种不熔化方式的优缺点及其对SiC纤维中氧含量的影响,并指出了制备高性能SiC纤维不熔化技术研究的国内外差距及发展趋势。

Different curing treatment methods of polycarbosilane fibres in the process of fabricating SiC ceramic fibres by preceramic polymer pyrolysis usually containing polymer synthesis, spinning, curing and pyrolysis, are reviewed in this paper. Current development situation of these manners is thoroughly presented. By comparing the element composition and mechanical properties of SiC fibre from different cross-linking manners, some advantages and drawbacks of these methods, and their effects on the oxygen content in SiC fibre are also discussed. Moreover, the developmental trend of cross-linking technique to fabricate excellent heat-resistant SiC fibres is proposed.