摘要
Ｃ６０与加热Ｌ－亮氨酸和十二醛去羧基化而得到的１，３－偶极体发生１，３－偶极环加成反应，得到一个带有长烷基链的Ｃ６０的吡咯烷单加成产物（产率３０％），并用ＦＴＩＲ、ＵＶ—Ｖｉｓ、ＥＩ—ＭＳ及循环伏安曲线法等谱图进行了表征．ＬＢ膜成膜性能的研究表明，π－Ａ曲线上产物的最小分子占有面积为０．５ｎｍ２．
Buckminsterfullerene(C60) underwent 1,3-dipolar cycloadditional reaction with 1,3 - dipole derived from heating L- leucine and dodecaldehyde by decarboxylic route. giving monoadduct pyrrolidine derivative of C. with a long alkyl group chain (in a yield of 30%). The structure of the product was characterized by spectra information. The study of the LB-film formation property suggested that the limiting molecular area of the product was about 0.5nm2.
出处
《延边大学学报（自然科学版）》
1996年第4期22-25,共4页
Journal of Yanbian University（Natural Science Edition）
关键词
LB膜
吡咯烷衍生物
碳60
成膜性能
制备
C60: 1,3 -dipolar cycloaddition: LB film
Pyrrolidine derivative
