钌（II）多吡啶配合物的合成及表征

Synthesis and Characterization of Some Ruthenium(Ⅱ) Polypyridine Complexes

以（ｂｐｙ）２Ｒｕ（ＡＦＯ）２＋，（ｐｈｅｎ）２Ｒｕ（ＡＦＯ）２＋（ｂｐｙ＝２，２′－联吡啶；ｐｈｅｎ＝１，１０－邻菲口罗啉；ＡＦＯ＝４，５－二氮杂芴酮）为先驱体，与苯肼，２，４－二硝基苯肼反应分别制得４种新的钌（Ⅱ）多吡啶配合物，用元素分析、红外光谱、紫外可见光谱、荧光光谱。

Four new ruthenium (Ⅱ) polypyridine complexes were prepared through the reaction of [(bpy) 2Ru(AFO)] 2+ /[(phen) 2Ru(AFO)] 2+ with phenylhydrazine/2, 4 dinitrophenylhydrazine. They were characterized by elemental analyses, electronic absorption, IR, emission spectra and cyclic voltammetry.