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环丙烷/Cope重排反应的研究进展 被引量:1

The Development of Tandem Cyclopropanation-Cope Rearrangement
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摘要 综述了环丙烷化/Cope重排反应合成七元环结构有机化合物的方法及研究进展。参考文献38篇。 The recent progress on the application of tandem cyclopropanation-Cope rearrangement in organic synthesis is reviewed with 38 references.
机构地区 广西大学化学系
出处 《合成化学》 CAS CSCD 1996年第4期358-365,共8页 Chinese Journal of Synthetic Chemistry
关键词 Cope重排 环丙烷化 七元环化合物 重排反应 s:α-Diazocarbonyl compounds, Cyclopropanation Cope rearrangent,Seven-memberedring compounds.
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  • 1Alvarez M, Pau R S, Svetlana A S, et al. Structure, Bioactivity and Synthesis of Natural Products with Hexahydropyrro [ 2,3-b ] indole [ J ]. Chem Eur J, 2011, 17 : 1388 - 1408.
  • 2Matsuura T, Overman L E, Poon D J. Catalytic asymmetric synthesis of either enantiomer of the calabar alkaloids physostigmine and physovenine[ J ]. J Am Chem Soc 1998,120 : 6500 - 6503.
  • 3Trost B M, Zhang Y. Molybdenum-catalyzed asymmetric allylation of 3-alkyloxindoles:Application to the formal total synthesis of ( - )-physostigmine [ J ]. J Am Chem Soc ,2006,128:4590 - 4591.
  • 4Depew K M, Marsden S P, Danishefsky S J, et al. Total Synthesis of 5-N-acctylardeemin and amauromine: Practical routes to potential MDR reversal agents [ J ]. J Am Chem Soc, 1999,121 : 11953 - 11963.
  • 5Huang A, Kodanko J J, Overman L E. Asymmetric synthesis of pyrrolidinoindolines. Application for the practical total synthesis of ( - )-phensefine [ J ]. J Am Chem Soc ,2004,126 : 14043 - 14053.
  • 6Bhat B, Harrison D M. The synthesis of ( -)-dihydroaszonalenin from L-tryptophsa ; the relative and absolute configuration of aszonalenin [ J].Tetrahedron, 1993,49 : 10655 - 10662.
  • 7Kawasaki T, Ogawa A, Takashima Y, et al. Enantioselective total synthesis of ( -)-pseudophrynaminol through tandem olefination, isomerization and asymmetric Clalsen rearrangement [ J ]. Tetrahedron, 2003,44 : 1591- 1593.
  • 8Song H, Yang J, Qin Y. Org synthesis of chiral 3-substituted hexahydropyrroloindoline via intermolecular cyclopropanation[ J]. Org Lett ,2006,8:6011 - 6014.

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