摘要
铜（Ⅰ）配合物［Ｃｕ（Ｃ８Ｈ４Ｏ２Ｆ３Ｓ）（ＰＰｈ３）２］合成、性质、晶体结构及反应机理的探讨王冬梅杨瑞娜侯益民金斗满＊（河南化学研究所，郑州４５０００３）关键词：铜粉三苯基膦晶体结构铜（Ⅰ）配合物在生理上是绝对重要的。有文献报道铜（Ⅰ）—亚酰配合物...
Reaction of copper powder with 2 thenoyltrifluoroacetone and PPh 3 yielded the complex [Cu(C 8H 4O 2F 3S)(PPh 3) 2], which have been characterized by elemental analysis and IR spectra. The crystal is monoclinic, space group P 2 1/ n , a=1.0584(1), b=1.6738(1), c=2.2728(9) nm; β =94.22(2); V =4.0152 nm 3; Z=4; D C=1.299 g·cm -3 ; R=0.048, R W=0.054. Copper (Ⅰ) ion is coordinated by two O and two P atoms forming distorted tetrahedron.
出处
《无机化学学报》
CSCD
北大核心
1996年第4期440-442,共2页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金
