摘要
本文报道一个吖啶-咪唑双功能配体L[9-(1-咪唑基)吖啶]的2个镉!配合物[Cd(L)2(NO3)2](1)和[Cd(L)2(Ac)(NO3)(H2O)](H2O)3(2)的合成及结构表征,并探讨了阴离子对配合物结构的影响,结果表明:不同的阴离子对配合物的结构具有重要影响。
Two new Cd(Ⅱ) complexes with acridine-imidazole ditopic ligand L (L=9-(1-imidazolyl)acridine), [Cd(L) 2(NO3)2] (1) and [Cd(L)2(Ac)(NO3)(H2O)](H2O)3 (2), were synthesized and structurally characterized by IR and single crystal X-ray structural analysis. 1 has a 1D chain structure bridged by NO3- anions, whereas 2 takes a mononuclear structure. The structural difference of the two complexes is attributable to the difference of counter anions. CCDC: 606068, 1; 606069, 2.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第8期1443-1448,共6页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20225101
20373028)