摘要
采用置换反应法制备镀银铜粉时,铜粉还原银氨溶液中的Ag+生成的Cu2+与NH3形成络合物[Cu(NH3)4]2+,它吸附于铜粉表面而阻碍还原反应的继续进行,使制备的镀银铜粉表层的银含量降低。用氨水提高银氨溶液的pH,可增加制备的镀银铜粉表层的银含量,提高其抗氧化性能。当用氨水调节银氨溶液的pH至11.50时,可制得表层银的质量分数高达47.91%且具有常温抗氧化性能的镀银铜粉。研究了pH、AgNO3用量、AgNO3浓度和反应温度对镀银铜粉的抗氧化性能的影响。
:The silver-coated copper powder was prepared with substitution reaction method. It was found that copper powder reduced Ag by producing [ Cu ( NH3 ) 4 ]^ 2 + that was absorbed onto the surface of the copper powder in the ammoniacal silver solution, which prevented the reduction reaction from proceeding. Therefore, as-prepared silver-coated copper powder has less silver content. Raising the pH value of ammoniacal silver solution with ammonia solution could increase the silver content of the prepared silver-coated copper powder and improve its oxidation-resistant performance. Thus, silver-coated copper powder with silver content of 47.91% could be prepared by adjusting the pH value of the ammoniacal silver solution to 11. 50. The influences of pH value, AgNO3 dosage , AgNO3 concentration and reaction temperature on oxidation resistance of the silver-coated copper powder were studied.
出处
《精细化工》
EI
CAS
CSCD
北大核心
2006年第8期738-742,共5页
Fine Chemicals
基金
国家自然科学基金(No.20271014
No.50372013)
"十五"国家科技攻关计划项目(No.2003BA310A24)
广东省自然科学基金(No.036918)~~
关键词
镀银铜粉
置换反应
抗氧化性能
silver-coated copper powder, substitution reaction, oxidation-resistant performance